By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov
This monograph is dedicated to the activation and diverse changes of saturated hydrocarbons (alkanes), i.e. reactions observed by means of the C--H and C--C bond cleavage. Alkanes are the most components of oil and common gasoline, and for that reason are the relevant feedstocks for the chemical undefined. nonetheless, those components are recognized to be the least reactive natural compounds. designated realization is paid to the lately came across alkane activations in the presence of steel complexes, that are defined in additional element. as well as the reactions of saturated hydrocarbons that are the major subject of this booklet, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph should be worthwhile not just in case you have an interest in the activation of alkanes and different hydrocarbons via steel complexes, but additionally for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few components of the monograph might be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally when you paintings within the petrochemical undefined, commercial natural synthesis and biotechnology.
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D) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R. H. Angew. , Int. Ed. Engl. 1993, 32, 789. (f) Heinekey, D. ; Oldham, W. , Jr. Chem. Rev. 1993, 93, 913. ; Perutz, R. N. Chem. Rev. 1996, 96, 3125. 3. 4. 5. 6. 7. 8. 9. (a) Sykes, P. A Guidebook to Mechanism in Organic Chemistry; Longman: London, 1971, Ch. 6. (b) Dneprovskiy, A. ; Temnikova, T. I. Theoretical Principles of Organic Chemistry, Khimiya: Leningrad, 1979, Chpts. 14, 15 (in Russian). (a) Taqui Khan, M. ; Martell, A. E.
RADIOLYSIS The interaction of high-energy irradiation with alkanes leads, at the first stage of the process, to the excitation of the hydrocarbon molecule [3a]. Furthermore, the excited molecule decomposes to generate free radicals and carbenes. Radiolysis of methane produces ethane, ethylene, and higher hydrocarbons: Transformations in the Absence of Metals 25 Pulse radiolysis of methylcyclohexane (MCH) gives rise to the formation of the solvent radical cation, but in argon-saturated MCH, the olefinic fragment cation is obtained [3b].
1931, 64B, 2844. (c) Milas, N. ; Sussman, S. J. Am. Chem. Soc. 1936, 58, 1302. (a) Kleiman, J. ; J. Am. Chem. Soc. 1963, 85, 1544. ; Davidson, J. M. J. Chem. Soc.. 1965, 843. ; Verberg, G. Recl. Trav. Chim. Pays-Bas 1965, 84, 1263. ; Danno, S. et al. J. Am. Chem. Soc. 1969, 91, 7166. (c) Garnett, J. ; Hodges, R J. J. Am. Chem. Soc. 1967, 89, 4546. 19 20 References for Chapter I 10. Gol’dshleger, N. ; Tyabin, M. ; Shilov, A. ; Shteinman, A. A. Zh. Fiz. Khim. 1969, 43, 2174 (in Russian). 11. (a) Gol’dshleger, N.
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov